3-(1H-Tetrazol-5-yl)pyridinium 3-(2H-tetrazol-5-yl)pyridinium dinitrate

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5-{40-[(5-Benzyl-2H-tetrazol-2-yl)- methyl]biphenyl-2-yl}-1H-tetrazole monohydrate

In the title compound, C22H18N8 H2O, the dihedral angle between the tetrazole rings is 69.58 (1) while the terminal phenyl ring makes dihedral angles of 26.98 (8) and 39.75 (8) with the other benzene rings. The rings of the biphenyl unit subtend a dihedral angle of 55.23 (8) . In the crystal, the solvent water molecule is linked to the main molecule via an N—H O hydrogen bond. In addition, C—H ...

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3-(1H-Tetra­zol-5-yl)pyridinium 3-(2H-tetra­zol-5-yl)pyridinium dinitrate

In the title compound, C(6)H(6)N(5) (+)·NO(3) (-), there are two different isomers of the cation within the asymmetric unit. The dihedral angles between the the pyridinium and tetra-zole rings are 2.54 (15) and 13.36 (18)° in the two cations. In the crystal, the packing of ions is stabilized by N-H⋯O and N-H⋯(O,O) hydrogen bonds, forming clusters composed of four ion pairs.

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Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex

The reaction of CoCl(2).6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network.

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Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN 2}manganese(II) dihydrate

The title compound, [Mn(C(4)H(3)N(8))(2)(H(2)O)(4)]·2H(2)O, represents the first structurally characterized transition metal complex of the 1,2-bis-(tetra-zol-5-yl)ethene ligand. The complex mol-ecule occupies a special position on an inversion centre and the Mn atom has a tetra-gonally distorted octa-hedral coordination. The bis-(tetra-zolyl)ethene ligand is planar within 0.0366 (7) Å. All 'ac...

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Tetra­aqua­bis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN 2}manganese(II) dihydrate. Corrigendum

The chemical name in the title of the paper by Hu [Acta Cryst. (2008), E64, m772] is corrected.[This corrects the article DOI: 10.1107/S1600536808012464.].

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s160053680901839x